Preheat oven to 425 degrees. Season chicken breasts with salt and pepper.
In a large nonstick skillet, heat olive oil over medium-high. Saute chicken until golden, 5 to 7 minutes , transferring batch to a rimmed baking sheet.
Bake until chicken is cooked through, about 25 minutes. Transfer to a large bowl.
Wipe skillet clean; add pineapple juice, ginger, and jalapeno. Cook over medium heat until syrupy and reduced to 3/4 cup, about 7 minutes. Pour sauce over chicken. Add scallions; toss to coat. Serve with white rice, if desired.
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